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Difference between revisions of "Conformational itinerary"
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A conformational itinerary is a description of the conformational changes that a molecule undergoes in changing from one conformation to another. In the case of a pyranose ring the conformational changes can be represented on a conformational map. Such a conformational map can be drawn as a polar projectin, centred on a chair conformation; alternatively, a Mercator-like projection can be drawn with conformations shown in a grid. For a more detailed discussion see the excellent book by J. Fraser Stoddard <cite>1</cite>. | A conformational itinerary is a description of the conformational changes that a molecule undergoes in changing from one conformation to another. In the case of a pyranose ring the conformational changes can be represented on a conformational map. Such a conformational map can be drawn as a polar projectin, centred on a chair conformation; alternatively, a Mercator-like projection can be drawn with conformations shown in a grid. For a more detailed discussion see the excellent book by J. Fraser Stoddard <cite>1</cite>. | ||
| − | [[Image:Conformation_map.png|centre]] | + | [[Image:Conformation_map.png|centre|600px]] |
<center>'''Chair/skew/boat/half-chair conformational polar projection'''</center> | <center>'''Chair/skew/boat/half-chair conformational polar projection'''</center> | ||
| + | <br> | ||
<br> | <br> | ||
| − | [[Image:Conformation_grid.png|centre]] | + | [[Image:Conformation_grid.png|centre|600px]] |
==References== | ==References== | ||
# Stereochemistry of Carbohydrates, J. Fraser Stoddart, John Wiley & Sons Inc, 1971, 264 pages. | # Stereochemistry of Carbohydrates, J. Fraser Stoddart, John Wiley & Sons Inc, 1971, 264 pages. | ||
[[Category:Definitions and explanations]] | [[Category:Definitions and explanations]] | ||
Latest revision as of 03:59, 30 April 2013
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A conformational itinerary is a description of the conformational changes that a molecule undergoes in changing from one conformation to another. In the case of a pyranose ring the conformational changes can be represented on a conformational map. Such a conformational map can be drawn as a polar projectin, centred on a chair conformation; alternatively, a Mercator-like projection can be drawn with conformations shown in a grid. For a more detailed discussion see the excellent book by J. Fraser Stoddard [1].
References
- Stereochemistry of Carbohydrates, J. Fraser Stoddart, John Wiley & Sons Inc, 1971, 264 pages.